Google Chrome by default follows or respects your Operating System’s (e.g., Windows 10) default app mode (Light or Dark). If you enable Dark app mode in Windows 10 Settings → Personalization → Colors, it also enables dark mode or dark theme in Google Chrome.

When you switch to the light mode in the Operating System, Chrome automatically switches to the light theme.
However, regardless of the Windows 10 app mode setting, you can force Google Chrome to always start in light mode or in dark mode. This article tells you how to prevent Google Chrome from respecting or following Windows 10’s app mode (Light vs Dark) setting. This can be done using additional/hidden chrome.exe command-line arguments which can be added to Chrome’s shortcut target field in Properties.Read more