When you click the Manage my network passwords link in the User Accounts applet in order to add or remove the stored credentials, the Stored User Names and Passwords dialog opens, but the command buttons may be grayed out. Also, the Add button may be missing.
This happens if the security Policy Do not allow the storage of credentials is enabled. To disable the Policy, use the steps below.
Network access: Do not allow the storage of credentials or .NET Passports for network authentication
[HKEY_LOCAL_MACHINE\SYSTEM\CurrentControlSet\Control\Lsa]
"disabledomaincreds"=dword:00000000